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MichiganState University

Science at the Edge

Engineering Seminar

*March 6^th , 2015*

11:30 a.m., Room1400 Biomedical and Physical Sciences Building

Refreshments served at 11:15 a.m.

*Mercouri G. Kanatzidis*

Professor of Chemistry

Northwestern University

  

*/Panoscopic all-scale architecturing for high performance thermoelectrics/*

*//*

Abstract

Thermoelectrics convert heat energy to electricity. The nanostructuring approach to highly efficient thermoelectrics has produced a
paradigm shift and ushered in a new era of investigation for efficient bulk thermoelectrics.  Increasing the thermoelectric figure of merit
can be accomplished via two general and effective approaches, nano- and meso-structuring to reduce the lattice thermal conductivity
  and altering the band structure to improve the power factor. Multiple methods of band structure engineering have been studied in this
field but those with the ability to change the relative energy levels of the band near the Fermi energy and capable of aligning the energy
level of the band structure of the a second phase added to the matrix are most effective.  By aligning the valence band of the matrix
and precipitate, high power factors can be maintained while reducing the lattice thermal conductivity by increasing phonon scattering
with nanoprecipitates of the secondary phase.  In the valence band of p-type PbQ (Q=S, Se, Te) thermoelectric materials have shown
large improvements in ZT by adding second phases which perform the functions of nano- and meso-structuring and at the same time
present good band alignment. This strategy has been demonstrated in several systems including p-type PbTe-SrTe, PbSe-(CdS/ZnS),
and PbS-CdS systems. Progress using this hierarchical panoscopic approach will be reviewed.

  

Bio

  

Mercouri Kanatzidis was born in Thessaloniki, Greece in 1957. After 
obtaining a B. Sc from Aristotle University in Greece, he received his 
Ph D. in chemistry from the University of Iowa in 1984. He was a 
post-doctoral research associate at the University of Michigan and 
Northwestern University from 1985 to 1987 and is currently the the 
Charles E. and Emma H. Morrison Professor of Chemistry at Northwestern 
University. Mercouri moved to Northwestern in the fall of 2006 from 
Michigan State University where he was a University Distinguished 
Professor of Chemistry since 1987.

Mercouri also holds an appointment at Argonne National Laboratory 
<http://www.anl.gov> and is the editor in chief of the Journal of Solid 
State Chemistry 
<http://www.sciencedirect.com/science?_ob=PublicationURL&_cdi=6922&_pubType=J&_auth=y&_acct=C000049540&_version=1&_urlVersion=0&_userid=965532&md5=f2a2281c5cf30e6b381942db3da16ec2>

For further information please contact Prof. Richard Lunt, Department of 
Chemical Engineering and Materials Science at [log in to unmask]

Persons with disabilities have the right to request and receive 
reasonable accommodation. Please call the Department of Chemical 
Engineering and Materials Science at 355-5135 at least one day prior to 
the seminar; requests received after this date will be met when possible.